Pwodwi Entwodiksyon
| 3-Enfòmasyon de baz Cyanopyridine |
| Non pwodwi: | 3-Syanopiridin |
| Sinonim: | NITRIL ASID NICOTIN; NITRIL NITRIL; NITRIL Asid NIKOTIN; SPECIFICATIONS AC-907/25014098;TIMTEC-BB SBB007554;IFLAB-BB F2108-0102;BETA-CYANOPYRIDINE;3-Azabenzonitrile |
| CAS: | 100-54-9 |
| MF: | C6H4N2 |
| mw: | 104.11 |
| EINECS: | 202-863-0 |
| Kategori pwodwi: | Entèmedyè famasetik; Piridin dérivés; Konpoze eterosiklik; bc0001 |
| Mol File: | 100-54-9.mol |
 |
|
| 3-Cyanopyridine Pwopriyete Chimik |
| Pwen k ap fonn | 48-52 degre (lit.) |
| Pwen bouyi | 201 degre (lit.) |
| dansite | 1.159 |
| endèks refraktif | 1.5242 (estimasyon) |
| Fp | 184 degre F |
| tanperati depo. | Atmosfè inaktif, Tanperati chanm |
| solubilite | 140g/l |
| fòm | Mass kristalin, kristal oswa fragman |
| pka | pK1:1.45(+1) (25 degre) |
| koulè | San koulè oswa blan a jòn |
| Solibilite dlo | 140 g/L (20 ºC) |
| BRN | 107711 |
| Limit ekspoze | NIOSH: IDLH 25 mg/m3 |
| Estabilite: | Enkonpatib ak ajan oksidan fò, ajan rediksyon fò, asid fò, baz fò. |
| InChiKey | GZPHSAQLYPIAIN-UHFFFAOYSA-N |
| Referans baz done CAS | 100-54-9(Referans baz done CAS) |
| Referans Chimi NIST | 3-Piridinkarbonitril(100-54-9) |
| Sistèm Rejis Sibstans EPA | 3-Piridinkarbonitril (100-54-9) |
| Enfòmasyon sou Sekirite |
| Kòd danje | Xn |
| Deklarasyon Risk | 22-36/37/38 |
| Deklarasyon Sekirite | 22-24/25-36/37/39-26 |
| WGK Almay | 3 |
| RTECS | QT3030000 |
| TSCA | Wi |
| Kòd HS | 29333999 |
| Done Sibstans Danjere | 100-54-9(Done Sibstans Danjere) |
| Enfòmasyon MSDS |
| Founisè | Lang |
|---|---|
| 3-Syanopiridin | angle |
| SigmaAldrich | angle |
| ACROS | angle |
| ALFA | angle |
| 3-Itilizasyon ak sentèz Cyanopyridine |
| Pwopriyete chimik | blan a bèlj solid |
| Pwopriyete chimik | Cyanopiridin yo se jan sa a: 2-syano-: Yon likid oswa solid blan ak tan. Zanmann odè. Pwen bouyi=2213 degre ; konjelasyon/pwen fizyon=27 degre ; pwen flash=89 degre . 3-cyano-: yon likid san koulè oswa yon solid kristal gri. |
| Itilizasyon | 3-Syanopiridin yo itilize nan preparasyon arylthiazolines ak arilimidazolines atravè kondansasyon dibromodimethylhydantoin katalize nan nitril aryl ak ethylene dyamin oswa aminoethanethiol. |
| Definisyon | ChEBI: Yon nitril ki se piridin ranplase pa yon gwoup cyano nan pozisyon 3. |
| Referans sentèz (yo) | Tetrahedron Letters, 29, p. 2155, 1988DOI: 10.1016/S0040-4039(00)86697-6 |
| Potansyèl ekspowisyon | Limit nan lè NIOSH IDLH525 mg/m3 NIOSH REL: (nitrile) 2 ppm, Konsantrasyon plafon, pa dwe depase nan nenpòt 15-minit peryòd travay. |
| Shipping | UN3276 Nitril, likid, toksik, non, Klas danje: 6.1; Etikèt: 6.1-Materyèl pwazon, non teknik obligatwa, danje potansyèl pou rale (dispozisyon espesyal 5). |
| Metòd pou pirifye | Li se rkristalize nan pwen k ap fonn konstan soti nan o-xylene / hexane. [Beilstein 22/2 V 115.] |
| Enkonpatibilite | Ajan oksidan, tankou pèrklorat, oksijene, ak pèrmanganat. Nitril ka polymerize nan prezans metal ak kèk konpoze metal. Yo enkonpatib ak asid; melanje nitril ak asid oksidan fò ka mennen nan reyaksyon trè vyolan. Nitril yo jeneralman enkonpatib ak lòt ajan oksidan tankou peroksid ak epoksid. Konbinezon baz ak nitril ka pwodui cyanide idwojèn. Nitril yo idrolize nan asid akeuz ak baz pou bay asid karboksilik (oswa sèl asid karboksilik). Reyaksyon sa yo jenere chalè. Peroksid konvèti nitril nan amid. Nitril ka reyaji kouray ak ajan rediksyon. Acetonitrile ak propionitrile yo idrosolubl nan dlo, men nitril ki pi wo pase propionitrile gen ba solubilite akeuz. Yo ensolubl tou nan asid akeuz. |
| 3-Pwodwi pou preparasyon Cyanopyridine ak matyè premyè |
| Matyè premyè | 4-Chlorobenzaldehyde-->Nicotinamide-->N-FENIL-1-NAFTILAMIN HYDROBROMIDE |
| Preparasyon pwodwi yo | Nicotinic acid-->Nicotinamide-->3-(AMINOMETHYL)PYRIDINE-->2-(3-PYRIDYL)-1,3-THIAZOLE-4-CARBOXYLIC ACID-->2-chloro-5-cyanopyridine-->3-Pyridinecarboxaldehyde-->2-(2-PYRIDINYL)-4-(TRIFLUOROMETHYL)-5-PYRIMIDINECARBOXYLIC ACID-->3-AMINOMETHYL-PYRIDINE-2-CARBOXYLIC ACID-->3-AMIDINOPYRIDINIUM CHLORIDE-->ETHYL 4-(TRIFLUOROMETHYL)-2-(PYRIDIN-2-YL)PYRIMIDINE-5-CARBOXYLATE-->3-(TERT-BUTOXYCARBONYLAMINO-METHYL)-PYRIDINE-2-CARBOXYLIC ACID-->3,3'-DIPICOLYLAMINE-->3-PYRIDINECARBOXAMIDINE-->3-CYANOPYRIDIN-4-YLBORONIC ACID-->3-[(N-(TERT-BUTYLOXYCARBONYL)AMINO)METHYL]PYRIDINE-->3-(Aminomethyl)pyridine-->3-PYRIDYLAMIDOXIME-->Methyl 2-(3-cyanopyridin-4-yl)acetate-->3-Pyridinemethanol-->Klori benziltrifenilfosfonyòm |
Baj popilè: 3-cyanopyridine, Lachin 3-syanopiridin manifaktirè, founisè, faktori
Pwochen: 3-Pikolin
Ou ka renmen tou
Voye rechèch
