Pwodwi Entwodiksyon
| Trifluoromethanesulfonyl chloride Enfòmasyon de baz |
| Non pwodwi: | Trifluoromethanesulfonyl klori |
| Sinonim: | TRIFLUORMETHANESULFONYL CHLORIDE;TRIFLUORMETHANESULFONYL CHLORIDE;TRIFLYL CHLORIDE;Methanesulfonyl lori, trifluoro-;PFC-MSC;Trifluoromathanesulfonyl chloride;Trifluoromethanesulfonylchloride,99%;trifluoromethylsulfonyl chloride |
| CAS: | 421-83-0 |
| MF: | CClF3O2S |
| mw: | 168.52 |
| EINECS: | 207-009-0 |
| Kategori pwodwi: | Dérivés Piperazine;konpoze organofluorin;Lòt;Pwoteje ak Derivatizasyon Reyaktif;Pwoteksyon ak Derivatizasyon |
| Mol File: | 421-83-0.mol |
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| Trifluoromethanesulfonyl klori Pwopriyete Chimik |
| Pwen k ap fonn | -26 degre |
| Pwen bouyi | 29-32 degre (lit.) |
| dansite | 1.583 g/mL nan 25 degre (lit.) |
| presyon vapè | 10.36 psi (20 degre) |
| endèks refraktif | n20/D 1.334(lit.) |
| Fp | 32 degre |
| tanperati depo. | 2-8 degre |
| solubilite | Klorofòm |
| fòm | Likid |
| koulè | Klè san koulè pou yon ti koulè |
| Espesifik gravite | 1.583 |
| Solibilite dlo | Idwolize ak dlo. |
| Sansib | Lakrimatwa |
| BRN | 1812016 |
| InChiKey | GRGCWBWNLSTIEN-UHFFFAOYSA-N |
| Referans baz done CAS | 421-83-0(Referans baz done CAS) |
| Enfòmasyon sou Sekirite |
| Kòd danje | C |
| Deklarasyon Risk | 14-34 |
| Deklarasyon Sekirite | 26-36/37/39-45 |
| RIDADR | UN 3265 8/PG 2 |
| WGK Almay | 3 |
| F | 10-21 |
| Nòt danje | Kowozif/Lakrimatwa |
| HazardClass | 8 |
| PackingGroup | II |
| Kòd HS | 29049090 |
| Enfòmasyon MSDS |
| Founisè | Lang |
|---|---|
| SigmaAldrich | angle |
| ACROS | angle |
| ALFA | angle |
| Trifluoromethanesulfonyl klori Itilizasyon ak sentèz |
| Pwopriyete chimik | Likid klè san koulè pou yon ti koulè |
| Itilizasyon | Ru (II) konplèks-katalize ajan trifluoromethylating pou aromat ak alkenes. |
| Aplikasyon | Trifluoromethanesulfonyl klori ka itilize kòm: Yon ajan trifluoromethylating pou fluoroalkylation heterocycles, arenes, ak heteroarenes. Yon ajan sulfonating pou alkòl. Yon ajan klò pou carbanions. |
| Sentèz | Ajoute 15 0g (1mol) asid trifluoromethanesulfonic nan raktor ekipe ak tèmomèt, aparèy distilasyon ak brase mekanik, ajoute tou dousman 435mL (6mol) klori thionyl anba beny glas, epi ajoute katalis N,N-dimethyl la. Formamide 7.36 (0.1 mol), tou dousman ogmante tanperati a nan tanperati chanm, brase pou demi èdtan, kontinye chofe jiska 40 degre, kontinye brase, reyaji pou 12 èdtan, ak Lè sa a, desann nan tanperati chanm apre reyaksyon an fini. Imedyatman, distilasyon vakyòm te pote soti nan 110 degre C. ak -0.1 a -0.08 MPa, ak an menm tan an, tanperati a te tou dousman leve soti vivan nan 50 degre C. jwenn 147 g. nan klori trifluoromethanesulfonyl, ak yon sede nan 87.5%. |
| Trifluoromethanesulfonyl chloride Preparasyon pwodwi ak matyè premyè |
| Preparasyon pwodwi yo | N-Phenyl-bis(trifluoromethanesulfonimide)-->2,2,3,3,3-PENTAFLUOROPROPYL TRIFLUOROMETHANESULFONATE-->1-NAPHTHYL TRIFLATE-->N-Hydroxynaphthalimide triflate-->1-(TRIFLUOROMETHANESULFONYL)IMIDAZOLE-->1-ADAMANTYL ISOTHIOCYANATE-->4-NITROPHENYL TRIFLUOROMETHANESULFONATE-->Methyl trichloroacetate-->Dyethyl chloromalonate |
Baj popilè: trifluoromethanesulfonyl klori, Lachin trifluoromethanesulfonyl klori manifaktirè, founisè, faktori
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