Pwodwi Entwodiksyon
| Ethyl 2-oxocyclopentanecarboxylate Enfòmasyon de baz |
| Non pwodwi: | 2-oxocyclopentanecarboxylate etil |
| Sinonim: | ETHYL-2-CYCLOPENTANONECARBOXYLATE;ETHYL 2-OXOCYCLOPENTANECARBOXYLATE;CYCLOPENTANONE-2-CARBOXYLIC ACID ETHYL ESTER;Ethyl 2-oxocyclopentanecarboxylate, tech., 90%Ethyl00GR; tech., 90% 25GR;2-Carbethoxycyclopentanone 2-Ethoxycarbonylcyclopentanone Cyclopentanone{-2-carboxylic Asid Ethyl Ester Ethyl Cyclopentanone-2-carboxylate 2-Oxocyclopentanone 2-Oxocyclopentathyl Ethyl Ester; 14}}oxocyclopentanecarboxylate,2-(Ethoxycarbonyl)cyclopentanon, Ethyl cyclopentane-2-carboxylate;Ethyl-2-cyclopentanonecarboxylate 10g [611-10-9] |
| CAS: | 611-10-9 |
| MF: | C8H12O3 |
| mw: | 156.18 |
| EINCS: | 210-253-0 |
| Kategori pwodwi: | Entèmedyè famasetik; BLOK KONSTRUCTION; C8 a C9; Konpoze Carbonyl; Sentèz chimik; Estè; pwodui chimik amann, pwodui chimik espesyal, entèmedyè, chimik elektwonik, sentèz òganik; pwodui chimik amann, pwodui chimik espesyal, entèmedyè, chimik elektwonik, sentèz òganik, materyèl fonksyonèl; Blòk Konstriksyon |
| Mol File: | 611-10-9.mol |
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| Pwopriyete chimik 2-oxocyclopentanecarboxylate etil |
| Pwen bouyi | 102-104 degre /11 mmHg (lit.) |
| dansite | 1.054 g/mL nan 25 degre (limen) |
| endèks refraktif | n20% 2FD 1.452 (lit.) |
| Fp | 172 degre F |
| tanperati depo. | Sele nan sèk, Tanperati chanm |
| fòm | Likid |
| pka | 12.02±0.20(Prevwa) |
| koulè | Klè san koulè a jòn pal |
| Solibilite dlo | ensolubl |
| retni | 387787 |
| InChiKey | JHZPNBKZPAWCJD-UHFFFAOYSA-N |
| Boutèy demè | 0.330 (est) |
| Referans baz done CAS | 611-10-9(Referans baz done CAS) |
| Referans Chimi NIST | Asid cyclopentanecarboxylic, 2-oxo-, ethyl ester (611-10-9) |
| Enfòmasyon sou Sekirite |
| Kòd danje | ksi |
| Deklarasyon Risk | 36/37/38 |
| Deklarasyon Sekirite | 23-24/25-36/37-26 |
| WGK Almay | 3 |
| F | 10 |
| HazardClass | IRITE |
| Kòd HS | 29183000 |
| Enfòmasyon MSDS |
| Founisè | Lang |
|---|---|
| 2-(Ethoxycarbonyl)cyclopentanon | angle |
| ATRAVÈ | angle |
| Sigmaaldrich | angle |
| ALFA | angle |
| Itilizasyon 2-oxocyclopentanecarboxylate ak sentèz |
| Pwopriyete chimik | likid klè san koulè ak jòn pal |
| Itilizasyon | Famasetik entèmedyè. |
| Itilizasyon | Ethyl 2-oxocyclopentanecarboxylate te itilize nan sentèz stereoselective nan (±)-cis, cis-spiro[4.4]nonane-1,6-dyol. Li te tou itilize nan sentèz la nan tanikolide. |
| Referans sentèz (yo) | Journal of the American Chemical Society, 85, p. 207, 1963DOI:10.1021/ja00885a021 Journal of Organic Chemistry, 55, p. 5037, 1990DOI:10.1021/jo00304a014 Tetrahedron Letters, 22, p. 1353, 1981DOI: 10.1016/S0040-4039(01)90316-8 |
| Deskripsyon jeneral | Faz-transfè reyaksyon benzylation nan etil 2-oxocyclopentanecarboxylate ak bromur benzyl nan mikroreaktè yo te envestige. Ethyl 2-oxocyclopentanecarboxylate patisipe nan oksidasyon konplèks baz kobalt (II) Schiff ki katalize nan alkòl prensipal ak segondè. |
| Danje | Vapè yo toksik, menm jan ak kontak po. |
| Ethyl 2-oxocyclopentanecarboxylate Preparasyon pwodwi ak matyè premyè |
| Matyè premyè | Tetrahydrofuran-->Acetic acid-->Sodium-->Toluene-->Potassium tert-butoxide-->Diethyl adipate-->Cyclopentanecarboxylic acid, 1-bromo-2-oxo-, ethyl ester-->1,4-Dioxaspiro[4.4]nonane-6-asid karboksilik, ester etilik |
| Preparasyon pwodwi yo | 3-Indolepropionic acid-->1-Cyclopentene-1-carboxylic acid, 2-(benzoylamino)-, ethyl ester-->Naphth[2,3-b]oxiren-2(1aH)-one, 7,7a-dihydro-7-hydroxy-1a,7-dimethyl--->2-CYCLOPENTANONE CARBOXYLATE-->3-oxo-2-pentylcyclopentaneacetic acid-->7-Hydroxy-2,3-dihydro-1H-cyclopenta[c]chromen-4-one-->MDL-29951-->Monoethyl Adipate |
Baj popilè: etil 2-oxocyclopentanecarboxylate, Lachin etil 2-oxocyclopentanecarboxylate manifaktirè, founisè, faktori
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