Pwodwi Entwodiksyon
| 4-Acryloylmorpholine Enfòmasyon de baz |
| Non pwodwi: | 4-Acryloylmorpholine |
| Sinonim: | ACRYLOYL MORPHOLINE;4-AKRYLOYLMORFOLINE;N-AKRYLOYLMORFOLINE;4-({1-oxo-2-propenyl)-Morpholine;N-Acrolylmorpholine;N-Acrylylmorpholine;ACRYYL MORPHOLINE;{{8} }} Acryloylmorpholine (estabilize ak MEHQ) |
| CAS: | 5117-12-4 |
| MF: | C7H11NO2 |
| mw: | 141.17 |
| EINECS: | 418-140-1 |
| Kategori pwodwi: | Acrylate;Acrylic Monomères;Monomère |
| Mol File: | 5117-12-4.mol |
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| 4-Propriyete chimik Acryloylmorpholine |
| Pwen k ap fonn | -35 degre (lit.) |
| Pwen bouyi | 158 degre 50mm |
| dansite | 1.122 g/mL nan 25 degre (lit.) |
| presyon vapè | 1.03-1.64Pa nan 25-29.9 degre |
| endèks refraktif | n20/D 1.512(lit.) |
| Fp | >230 degre F |
| tanperati depo. | 2-8 degre |
| solubilite | Soluble nan dlo |
| pka | {{0}}.08±0.20(Prevwa) |
| fòm | Likid |
| koulè | San koulè a jòn |
| Solibilite dlo | 1000g / L nan 20 degre |
| Sansib | Limyè sansib |
| BRN | 119302 |
| InChiKey | XLPJNCYCZORXHG-UHFFFAOYSA-N |
| LogP | -0.46 nan 20.5-21 degre |
| Referans baz done CAS | 5117-12-4(Referans baz done CAS) |
| Referans Chimi NIST | N-akriloilmorfolin (5117-12-4) |
| Sistèm Rejis Sibstans EPA | Morfolin, 4-(1-oxo-2-propenil)- (5117-12-4) |
| Enfòmasyon sou Sekirite |
| Kòd danje | Xn |
| Deklarasyon Risk | 22-41-43-48/22 |
| Deklarasyon Sekirite | 23-26-36/37/39 |
| WGK Almay | 2 |
| TSCA | Wi |
| Kòd HS | 29349990 |
| Enfòmasyon MSDS |
| Founisè | Lang |
|---|---|
| SigmaAldrich | angle |
| ALFA | angle |
| 4-Itilizasyon ak sentèz Acryloylmorpholine |
| Pwopriyete chimik | 4-Acryloylmorpholine gen yon pwen k ap fonn ?35 degre epi li se likid klè nan tanperati chanm. Nan 25 degre, li gen yon dansite de 1.122 g/mL. Li bezwen estoke nan 2-8 degre. |
| Itilizasyon | 4-Acryloylmorpholine yo itilize nan adhésifs, UV geri rezin, penti endistriyèl, lank enprime UV, polymère rekiperasyon lwil oliv, medsin ak pwodui chimik komodite. |
| Reyaksyon | Lè l sèvi avèk kataliz cobalt, diethylzinc ankouraje rediksyon konjige 4-acryloylmorpholine pou pwodui enolat etilzink ki koresponn lan, ki reyaji ak N-tosyl aldimines pou peye -aminoamid.[1]. |
| Enflamabilite ak eksplozibilite | Ki pa ka pran dife |
| Sentèz | Yo te ajoute yon solisyon {{0}}.04 mol amine ki koresponn lan nan 20 ml klori metilèn anidrid tou dousman nan 0-5??C a 0.02 mol klori akriloil nan 20 ml metilèn anidrid. klori. Yo te brase melanj lan pou 3 èdtan nan tanperati chanm nan yon atmosfè inaktif, epi presipite a te filtre epi lave ak klori metilèn (2 a 10 ml). Kouch òganik la te lave nan siksesyon ak 5 ml dlo ak 5 ml nan yon solisyon satire nan NaHCO3 epi cheche sou Na2SO4, yo te retire sòlvan an anba presyon redwi, epi rezidi a te pirifye pa kolòn kwomatografi sou jèl silica lè l sèvi avèk hexane-etil acetate. (5 : 1 a 1 : 1) kòm eluyan. 4-Acryloylmorpholine, Sede 1.78 g (63%). IR spectre, |í, cm-1: 2857, 1647, 1612, 1439, 1263, 1238, 1115, 1038, 953. spectre 1H RMN, |?, ppm: 3.51-3.73 m (8H, NCH2CH2O), 5.72 dd (1H, 3-Hcis, 3J=10.6, 2J=1.9 Hz), 6.29 dd (1H, 3-Htrans, 3J=16.7, 2J=1.9 Hz), 6.57 dd (1H, 2- H, J=16.7, 10.6 Hz). spectre 13C NMR, |?C, ppm: 41.74 ak 45.66 (CH2N), 66.22 (CH2O), 126.64 (C2), 127.69 (C3), 164.92 (C1). Spectre mas, m/z (Irel, %): 141 (36) [M]+, 140 (12), 126 (58), 112 (22), 111 (15), 110 (15), 109 (12) , 98 (10), 96 (26), 86 (72), 83 (13), 70 (14), 68 (14), 57 (17), 56 (86), 55 (100), 42 (23). Fig. Metòd sentetik 2 4-Acryloylmorpholine |
| Referans | [1] PRIETO O, LAM H W. Cobalt-catalyzed rediksyon Mannich reyaksyon nan 4-acryloylmorpholine ak N-tosyl aldimines??[J]. Organic & Biomolecular Chimi, 2007. DOI:10.1039/B715839D. |
Baj popilè: 4-acryloylmorpholine, Lachin 4-acryloylmorpholine manifaktirè, founisè, faktori
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