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Pwodwi

Kay / Pwodwi / Chimi òganik
4-Klorotiofenol

4-Klorotiofenol

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Pwodwi Entwodiksyon

 
4-Chlorothiophenol Enfòmasyon de baz
Non pwodwi: 4-Klorotiofenol
Sinonim: 4-Chlorothiophenol/4-Chlorobenzenethiol;4-Cyano-Acetophonene/4-CA;4-Kloro;4-Chlorothiophenol 99%;{{8} }chlorthiophenol;PARA-CHLOROTHIOPHENOL;BENZENETHIOL,PARA-CHLORO-;4-CHLOROTIOPENOL
CAS: 106-54-7
MF: C6H5ClS
mw: 144.62
EINCS: 203-408-9
Kategori pwodwi: Phenol&Thiophenol&Mercaptan;Fenol ak tiofenol;Fenol aromat;K00001
Mol File: 106-54-7.mol
4-Chlorothiophenol Structure
 
4-Chlorothiophenol Pwopriyete Chimik
Pwen k ap fonn 49-51 degre (lit.)
Pwen bouyi 205-207 degre (lit.)
dansite 1.1911
endèks refraktif 1.5480
Fp >230 degre F
tanperati depo. 2-8 degre
solubilite metanol: idrosolubl
pka pK1:5.9 (25 degre)
fòm Solid kristalin
koulè Blan prèske blan
Solibilite dlo ensolubl
Sansib fetidite/lakrimatwa
retni 605971
InChiKey VZXOZSQDJNBRC-UHFFFAOYSA-N
Referans baz done CAS 106-54-7(Referans baz done CAS)
Referans Chimi NIST Benzenethiol, 4-kloro-(106-54-7)
Sistèm Rejis Sibstans EPA Benzenethiol, 4-chloro- ({{2}%)
 
Enfòmasyon sou Sekirite
Kòd danje C
Deklarasyon Risk 22-34-36/37-20/21/22
Deklarasyon Sekirite 26-36/37/39-45-27
RIDADÈ UN 3261 8/PG 2
WGK Almay 3
RTÈK YO DC1050000
F 9-13-23
Nòt danje Kowozif / Lakrimatwa / fetidite
tSCA Wi
HazardClass 8
Pake Group III
Kòd HS 29309090
 
Enfòmasyon MSDS
Founisè Lang
4-Klorotiofenol angle
ATRAVÈ angle
Sigmaaldrich angle
ALFA angle
 
4-Chlorothiophenol Itilizasyon ak sentèz
Pwopriyete chimik blan a prèske blan solid cristalline
Itilizasyon Aditif lwil oliv, pwodui chimik agrikòl, plastifyan, pwodui chimik kawotchou, koloran, ajan mouye, ak estabilize.
Itilizasyon 4-Chlorothiophenol te itilize pou modifye poly(klori vinil) ak pou fè sentèz poly(klori vinil) ak gwoup alojene.
Referans sentèz (yo) Journal of Organic Chemistry, 27, p. 4455, 1962DOI:10.1021/jo01059a081
Kominikasyon sentetik, 18, p. 575, 1988DOI: 10.1080/00397918808064014
Deskripsyon jeneral 4-Chlorothiophenol sibi kouple oksidatif ki katalize pa fè (III)-tetra phenyl prophyrin pou fòme disulfid.
Danje Toksik pa enjèstyon.
Metòd pou pirifye Rekristalize thiophenol a soti nan EtOH akeuz. Etè SMe a gen m 129o ak etè SEt gen m 64o. [D'Sousa et al. J Org Chem 52 1720 1987, Beilstein 6 H 326, 6 I 149, 6 III 1034.]
 
4-Pwodwi preparasyon klorotyofenol ak matyè premyè
Matyè premyè Sulfuric acid-->Chlorosulfonic acid-->Klorbenzèn
Preparasyon pwodwi yo (5-CHLORO-1-BENZOTHIOPHEN-3-YL)METHYLAMINE-->(5-CHLORO-1-BENZOTHIOPHEN-3-YL)METHANOL-->3-(Bromomethyl)-5-chlorobenzo[b]thiophene-->5-CHLORO-BENZO[B]THIOPHENE-3-CARBOXYLIC ACID-->5-CHLORO-3-METHYLBENZO[B]THIOPHENE-2-SULFONAMIDE-->5-CHLORO-3-METHYLBENZO[B]THIOPHENE-2-SULFONYL CHLORIDE-->1-(5-CHLOROBENZO[B]THIOPHEN-3-YL)ETHANONE-->5-CHLORO-3-METHYLBENZO[B]THIOPHENE-->2-Chlorothioxanthone-->5-CHLOROBENZOTHIOPHENE-->CARBOPHENOTHION-->2-CHLORO-9-(3-(DIMETHYLAMINO)PROPYL)-TH&-->(4-CHLOROPHENYLTHIO)ACETONE-->CHLOROMETHYL 4-CHLOROPHENYL SULFIDE-->4-(4-CHLOROPHENYLTHIO)-3-NITROBENZALDEHYDE-->2-(4-chlorophenylthio)benzoic acid-->2-ACETYL-4'-CHLORO DIPHENYL SULFIDE-->4-CHLOROPHENYLSULFONYLACETONITRILE
 

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